热等静压处理对K439B高温合金显微组织的影响

对K439B合金进行了1165 ℃/150 MPa,4 h热等静压处理,采用光学显微镜和扫描电镜对比研究了铸态和热等静压态K439B合金的显微组织。结果表明:铸态K439B合金存在0.25%的显微疏松,热等静压后显微疏松基本消除(0.013%)。与铸态相比,经过热等静压处理后合金中的γ/γ′共晶组织体积分数和尺寸减小,各元素分布更加均匀,凝固偏析系数均更接近1。铸态K439B合金枝晶干处γ′相尺寸和体积分数分别是116.9 nm和17.8%,枝晶间部位γ′相尺寸和体积分数分别为244.4 nm和24.9%。热等静压后合金枝晶干部位的γ′相尺寸及体积分数分别为148.0 nm和17.5%,枝晶间部位γ′相尺寸和体积分数分别为159.1 nm和22.8%。热等静压处理使合金枝晶干、枝晶间部位的γ′相尺寸、体积分数和形貌接近,同时γ′相分布变得均匀。     

固溶处理对2205双相不锈钢组织及钝化膜特性的影响

用不同温度对2205双相不锈钢进行固溶处理,利用定量金相法及硬度法、电化学极化试验、电化学阻抗谱试验的方法研究固溶温度与2205双相不锈钢微观组织和钝化膜特性之间的关系。结果表明,当固溶温度为950 ℃时,有σ相存在,分布于铁素体/奥氏体晶界,当固溶温度为1000 ℃时,σ相消失,铁素体相比例随固溶温度的升高而升高,奥氏体相比例则呈相反规律;电化学试验和阻抗谱试验结果显示,材料在950 ℃时钝化膜稳定性和耐蚀性能最差,在1050 ℃时钝化膜稳定性和耐蚀性能最好。     

温轧温度对中碳Cr-Mo钢组织性能的影响

通过SEM、EBSD和拉伸试验研究了温轧温度对中碳Cr-Mo钢组织演变和力学性能的影响。结果表明:较高温轧温度有利于Cr-Mo钢组织的均匀分布,当轧制温度从500 ℃增加到600 ℃时,铁素体晶粒尺寸由0.424 μm增加到0.490 μm,晶粒尺寸差别不断减小,屈服强度由1380 MPa下降至1062 MPa,在550 ℃轧制试验钢的塑性最好,强塑积最高,为5816 MPa·%。     

The study of palm‐oil‐based bio‐polyol on the morphological,acoustic and mechanical properties of flexible polyurethane foams

The focus of this paper was to explore the acoustic properties of flexible polyurethane (FPU) foam modified by palm‐oil‐based polyol (POP). The presence of POP showed a marked influence on the microstructure and mechanical properties of FPU foam. A smaller mean pore diameter can be observed at lower POP content. Indeed, the introduction of POP caused a higher closed pore ratio and an increased air‐flow resistivity, which consequently improved the sound absorption coefficient and transmission loss. In particular, the acoustic performance of the all bio‐based FPU foam was enhanced at low frequency, and the density was lower than that of the reference foam. Additionally, the addition of POP also improved the compressive strength. Conversely, the tensile strength of FPU foam declined with increasing POP content. From this study, the outstanding acoustic ability of bio‐based FPU foam has been proved, with additional advantages of lower density and higher compressive strength. © 2019 Society of Chemical Industry     

Flame spectroscopy of waste tire oils and waste cooking oils blends using coaxial burner

Waste tires and cooking oil pose a serious danger to human health and environment. Self-reacting pyrolysis system for waste tires is designed and constructed for converting waste tires into oil that could be used as a sustainable fuel. This study aims to analyze the thermal microstructure of conventional fuels like light diesel oil (LDO) and heavy diesel oil (HDO) as well as blended with waste cooking oil (WCO) and tires pyrolysis oil (TPO) using a co-axial burner via flame spectroscopy analysis. The first Blend 1 (B1) consists of 20% WCO + 80% LDO, the second one (B2) consist of 20% WCO+80%HDO and the last one (B3) was 20%TPO and 80% LDO by mass. This percentage was chosen carefully and according to previous combustion characteristics results. The experimental results showed that B1 will shrink C2 radicals by nearly 61% and 64.5% at Ф = 0.63 and 0.96 respectively. B2 will decrease C2 radicals by nearly 19% and 82% at Ф = 0.63 and 0.96 respectively. Finally, B3 will reduce C2 radical's intensity by nearly 39% and 58% at Ф = 0.63 and 0.96 respectively. TPO produced CH emission radicals lower than that of LDO by nearly 5.9%. LDO droplets absorbed more radiation energy needed for excitation than that of WCO due to droplet size and fuel physic-chemical properties. B2 fuel is recommended to replace LDO at Ф = 0.63 and 0.96.     

淬火温度对G105钢组织和性能的影响

利用硬度计、拉伸试验机、冲击试验机和光学显微镜等手段,研究了G105钢分别在890、910和930 ℃保温150 min淬火,随后进行630 ℃保温180 min回火处理后组织和性能变化。结果表明:随着淬火温度的升高,G105钢淬火硬度越来越高;经回火处理后,淬火温度为890 ℃和910 ℃时,调质硬度无太大差异,分别为33.2 HRC和32.7 HRC,淬火温度为930 ℃的调质硬度相对提高约1.5 HRC。试验钢强度随着淬火温度的升高也呈现升高趋势,但冲击韧性呈先升高后下降的趋势,这主要是由于调质后存在粒状碳化物的析出现象,导致其冲击韧性显著下降,故认为当淬火温度选取910 ℃时,获得的G105钢综合力学性能较佳。     

Effects of Al content on the corrosion properties of Mg–4Y–xAl alloys

The corrosion performances of Mg–4Y–xAl (x = 1, 2, 3, and 4 wt%) alloys in the 3.5% NaCl electrolyte solution are investigated by electrochemical tests, weight loss measurement and corrosion morphology observation. The results indicate that corrosion modes for the alloys are localized corrosion and the filiform type of attack. With Al concentration increasing from 1 to 4 wt%, the corrosion rate of Mg–4Y–xAl alloys decreases firstly and then increases, and WA42 alloy shows the best corrosion resistance. The addition of Al element to Mg–4Y alloys leads to the formation of Al₂Y and Al₁₁Y₃ intermetallic compounds and reduces the proportion of Mg₂₄Y₅ phase. Corrosion resistance of the Mg–4Y–xAl alloys mainly depends on the size and distribution of the second phases. Besides, the addition of excessive Al can greatly consumes the Y element in the matrix, thus leading to a less protective film on the alloys. The effect of the relative Volta potential changes between the second phases and α-Mg on corrosion resistance of Mg–4Y–xAl alloys is insignificant. The main corrosion products of the Mg–4Y–xAl alloys are Mg(OH)₂, Mg₃(OH)₅Cl·4H₂O, Mg_0.72Al_0.28(CO₃)_0.15(OH)_1.98(H₂O)_0.48, and Mg₄Al₂(OH)₁₂CO₃·3H₂O.     

微观组织对2A14铝合金轮毂力学性能和腐蚀性能的影响

通过电子背散射衍射(EBSD)、场发射扫描电子显微镜(SEM)、透射电子显微镜(TEM)、室温拉伸、浸泡腐蚀、电化学极化等测试分析方法，研究了2A14铝合金轮毂内部不同区域上微观组织的差异及其对力学性能和腐蚀性能的影响。结果表明，2A14铝合金轮毂的芯部和1/4层的晶粒尺寸分别是113和54 μm，再结晶分数分别是16%和36%。1/4层的合金相和时效析出相的含量都大于芯部，其中两种时效析出相(θ’和Q相)的数量密度均为芯部的2倍左右。芯部具有较大的晶粒尺寸和较少的时效析出相，因此具有较低的力学性能。同时，芯部相对于1/4层具有较少的合金相和较大的晶界相间距，因而芯部的电化学腐蚀和晶间腐蚀倾向均低于1/4层。     

辊速差对连铸连轧7075铝板显微组织、织构及力学性能的影响

研究辊速差对连铸连轧7075铝板显微组织、织构及力学性能的影响。采用3种不同上辊/下辊转速比(ω/ω0,ω为上辊转速,ω0为下辊转速)1:1、1:1.2及1:1.4进行多次试验。结果显示,在最大辊速差条件下(ω/ω0=1:1.4),7075铝板在轧制方向的屈服强度和极限抗拉强度分别提高41.5%和21.9%。此外,当辊速比ω/ω0为1:1.4时,成品轧制板的平均晶粒尺寸减小36%,横剖面平均硬度增加约9.2%。织构研究结果显示,辊速差越大,成品各向同性及硬度越大。然而,采用不同辊速度的连铸连轧会导致变形板伸长率降低约6%。     

Effect of baking in different ovens on the quality and structural characteristics of saltine crackers

The aim of the study was to evaluate the physical and microstructural characteristics of crackers baked in four different industrial baking ovens (indirect radiation-cyclotherm, indirect convection, hybrid and industrial tunnel-ITO). Indirect convection and cyclotherm ovens provide the highest (5685.43 ± 51 W m⁻²) and the lowest (4860 ± 38.87 W m⁻²) amount of heat flux, respectively. Despite the amount of heat flux, indirect convection led to crackers with the highest moisture (7.86% vs. 4.82% in clyclotherm) and specific volume, but the lowest hardness. Cyclotherm resulted in crackers with lower specific volume, surface area, porosity, smooth and regular surface. Conversely, the hybrid and ITO ovens showed closer heat flux, leading to crackers with similar moisture content, texture parameters, specific volume, browning and inner porosity. Overall results show the potential of baking using different ovens for modifying the quality parameters of the crackers.